Silicone Basics:
Silicone rubber is a unique synthetic elastomer made from a cross-linked polymer which is reinforced with silica. Its characteristics are such that it provides a balance of mechanical and chemical properties useful for bonding glass aquariums (not acrylic).
The basic formula is: Me3SiO(SiMe2O)nSiMe3
RTV Silicones are the silicones commonly used for glass construction and is often sold in Home Improvement and Pet Stores (or online)
Different formulas and (combined with temperature and outside humidity) will affect cure time. Dow Corning and GE have proprietary formulas that cure at an even slow rate as compared to some cheaper formulas, especially used in construction where this is not an important factor.
100% RTV Silicone Rubber Sealant produces a flexible, durable weather resistant seal between similar and dissimilar materials; RTV Silicone provides excellent adhesion to tile, glass, porcelain, ceramic, fiberglass, non-oily woods, plaster, painted surfaces, metal, many plastics, and rubber. It will withstand temperature extremes from -60°F. to +450°F. and is waterproof for freshwater or saltwater use.
You will note that plastic (which is made from oil) is not mentioned. RTV silicone is not useful for bonding acrylic aquariums and the oils within acrylic will eventually cause peeling away (lack of adhesion).
Aquarium Applications:
RTV Silicones are useful in the construction of glass aquariums and sealing the joints in DIY wooden aquariums. Silicone is NOT useful for acrylic aquariums as it will peel away over time due to the inherent oils in plastics.
Not all silicone formulas are the same, as stated earlier, Dow Corning and GE produce a RTV silicone that cures at an even and slow rate necessary for aquariums. Why is this important? Too fast a cure will not allow proper surface adhesion especially in important seams. It is also hard to work with in building aquariums and the person needs to work very quickly (usually too quickly) for proper aquarium construction.
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